Spontaneity in gas equations  [ENDORSED]


Moderators: Chem_Mod, Chem_Admin

nelms6678
Posts: 53
Joined: Fri Sep 29, 2017 7:07 am

Spontaneity in gas equations

Postby nelms6678 » Wed Mar 14, 2018 10:29 am

If you're measuring spontaneity in the amount of moles of gas in an equation for example:
2 N2O(g)—> N2(g) + O2(g)

If the amount of moles are equal on both sides what does that tell about delta S?

Chem_Mod
Posts: 23858
Joined: Thu Aug 04, 2011 1:53 pm
Has upvoted: 1253 times

Re: Spontaneity in gas equations  [ENDORSED]

Postby Chem_Mod » Wed Mar 14, 2018 11:31 am

Generally speaking, if the number of moles of gas increases in a reaction, this tends to increase the entropy. However, the only way to be sure is to calculate ΔS for the reaction.

If both sides have equal numbers of moles, then you must use another criterion to predict the sign of the entropy change for the reaction such as phase changes or molecular complexity. Again, the only way to be sure is to calculate ΔS for the reaction using standard molar entropies.


Return to “Concepts & Calculations Using Second Law of Thermodynamics”

Who is online

Users browsing this forum: No registered users and 9 guests