Moderators: Chem_Mod, Chem_Admin

Briana Yik 1H
Posts: 30
Joined: Fri Sep 28, 2018 12:20 am


Postby Briana Yik 1H » Thu Feb 07, 2019 12:06 pm

In degeneracy, when W=X^N, what does the x represent and how do we figure it out?

Posts: 29
Joined: Fri Sep 28, 2018 12:19 am

Re: Degeneracy

Postby lizettelopez1F » Thu Feb 07, 2019 12:33 pm

X represents the number of states and I believe that the number of states will always be given to us

Parth Mungra
Posts: 72
Joined: Fri Sep 28, 2018 12:28 am

Re: Degeneracy

Postby Parth Mungra » Thu Feb 07, 2019 12:53 pm

X represents the number of locations that the atoms (the number of atoms is n) can be in.

Posts: 55
Joined: Fri Sep 28, 2018 12:20 am

Re: Degeneracy

Postby chloewinnett1L » Sat Feb 09, 2019 3:13 pm

We did a problem at a PL session where the number of states wasn't explicitly given, but we were given the chemical formula of the molecule. In this case, you would draw out every possible orientation of the molecule. Think Lewis structures/molecular geometry. For example, the molecule SO2F2 has six different orientations because the F and O atoms are situated around the S atom and can be arranged in 6 different ways. I don't know how to draw a picture on here, so think of the following as 12:00, 3:00, 6:00, and 9:00, respectively: OFOF, FFOO, OOFF, FOFO, FOOF, OFFO. The LA said that if we were asked to determine the number of states on a test given the chemical formula, it probably wouldn't be any more complicated than this.

Hope this makes sense!

Andrew Bennecke
Posts: 62
Joined: Fri Sep 28, 2018 12:15 am

Re: Degeneracy

Postby Andrew Bennecke » Sun Feb 10, 2019 8:49 pm

The X represents the number of possible orientations in which a molecule could exist. If we were to draw every resonance structure of a molecule (Ignoring changes in bond order), they would each represent a different orientation of the molecule.

Return to “Concepts & Calculations Using Second Law of Thermodynamics”

Who is online

Users browsing this forum: No registered users and 1 guest