∆S surroundings ?


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Bella Wachter 1A
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∆S surroundings ?

Postby Bella Wachter 1A » Sat Mar 13, 2021 9:11 am

When is ∆S surroundings = 0?

Is it for any irreversible expansion or solely irreversible free expansions? And does this irreversible expansion have to be isothermal?

Jay Solanki 3A
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Re: ∆S surroundings ?

Postby Jay Solanki 3A » Sat Mar 13, 2021 10:24 am

deltaS of the surroundings is 0 for all irreversible expansions/compressions. Free expansions do no work (since the expansion occurs against an external pressure of 0) and are adiabatic so q=0 as well. Since there is no energy transfer between the system and the surroundings, delta S of the system, surroundings, and universe is 0. Correct me if I am wrong anyone, but hope this helps!


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