Residual entropy

Boltzmann Equation for Entropy:

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Sei Lam 3F
Posts: 51
Joined: Fri Sep 29, 2023 12:21 pm

Residual entropy

Postby Sei Lam 3F » Tue Feb 20, 2024 10:49 pm

What exactly contributes to the residual entropy of a substance?

905935806
Posts: 100
Joined: Fri Sep 29, 2023 12:12 pm

Re: Residual entropy

Postby 905935806 » Tue Feb 20, 2024 10:50 pm

The residual entropy of a substance is contributed by the disorder or randomness present in the arrangement of its particles, particularly at low temperatures where the system doesn't fully settle into its lowest energy state.

106050998
Posts: 46
Joined: Mon Jan 09, 2023 1:09 am

Re: Residual entropy

Postby 106050998 » Tue Feb 20, 2024 11:12 pm

Residual entropy is brought about by attempting to bring the system to as low a temperature as possible(T=0) and the microstates and positions that occur as it goes down to that lower energy state.

406003397
Posts: 58
Joined: Mon Jan 09, 2023 2:04 am

Re: Residual entropy

Postby 406003397 » Thu Mar 14, 2024 3:00 am

Residual entropy refers to the entropy present in a crystalline substance at absolute zero temperature (0K), resulting from the substance's inherent disorder in its perfectly ordered state. This disorder can stem from different equivalent arrangements of the atoms or molecules within the crystal that are indistinguishable energetically but contribute to the overall entropy due to their multiplicity, leading to a non-zero entropy value even at 0K.


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