Irreversible Vs. Reversible Expansion

Boltzmann Equation for Entropy:

Moderators: Chem_Mod, Chem_Admin

Natalie LeRaybaud 1G
Posts: 54
Joined: Thu Jul 13, 2017 3:00 am

Irreversible Vs. Reversible Expansion

Postby Natalie LeRaybaud 1G » Tue Feb 06, 2018 12:42 pm

Can someone please explain the difference between irreversible and reversible expansion and the effect it has when calculating entropy? I saw the diagrams of each posted on the website but now I feel a bit more confused on the subject.

Clarisse Wikstrom 1H
Posts: 63
Joined: Fri Sep 29, 2017 7:05 am

Re: Irreversible Vs. Reversible Expansion

Postby Clarisse Wikstrom 1H » Tue Feb 06, 2018 1:40 pm

Irreversible is spontaneous in one direction, and is highly unlikely to proceed in reverse. It does less work than reversible expansion because it is typically expanding on a lower pressure. On the other hand, you can think of a reversible expansion as equally proceeding in both directions because the pressure equal. Because it is expanding on the same pressure rather than lower pressure, reversible expansion does more work than irreversible expansion.

Lindsay Kester 2L
Posts: 29
Joined: Thu Jul 27, 2017 3:00 am

Re: Irreversible Vs. Reversible Expansion

Postby Lindsay Kester 2L » Tue Feb 06, 2018 3:06 pm

However, entropy is a state function, so regardless of whether it's irreversible or reversible expansion, it's going to have the same entropy at the end, and you can use the same formulas.


Return to “Third Law of Thermodynamics (For a Unique Ground State (W=1): S -> 0 as T -> 0) and Calculations Using Boltzmann Equation for Entropy”

Who is online

Users browsing this forum: No registered users and 2 guests