isothermal reversible vs. isothermal irreversible

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Donovan McGraw 2C
Posts: 86
Joined: Fri Sep 29, 2023 11:13 am

isothermal reversible vs. isothermal irreversible

Postby Donovan McGraw 2C » Thu Feb 22, 2024 5:51 pm

Why does an isothermal reversible vs. isothermal irreversible system affect the value of delta S total?

carolineselliott2D
Posts: 45
Joined: Thu Nov 23, 2023 8:29 am

Re: isothermal reversible vs. isothermal irreversible

Postby carolineselliott2D » Thu Feb 22, 2024 5:51 pm

In a reversible reaction, since it happens so slowly and in “infinite” intervals, the total delta S is equal to 0 because (delta)S surroundings equals the negative of (delta)S system. In a reversible reaction, since the reaction is meant to occur very quickly, the (delta)S surroundings is equal to 0 and (delta)S total = (delta)S system.

Denise Mora 1C
Posts: 41
Joined: Tue Nov 14, 2023 8:59 am

Re: isothermal reversible vs. isothermal irreversible

Postby Denise Mora 1C » Sun Mar 17, 2024 9:49 pm

Hi, an isothermal reversible process is represented by the equation: delta Ssys = -delta Ssurr. This is because the delta Stotal is set to 0 since any increase in the entropy of the system is balanced by a decrease in the entropy of the surroundings. An isothermal irreversible process involve irreversible changes and lead to an overall increase in entropy.


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