change in entropy when t=0k

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Denise Mora 1C
Posts: 41
Joined: Tue Nov 14, 2023 8:59 am

change in entropy when t=0k

Postby Denise Mora 1C » Sun Mar 17, 2024 9:39 pm

Are we able to calculate the change of entropy of a system when it is at a temperature of 0 K?

106062642
Posts: 42
Joined: Wed Nov 15, 2023 9:21 am

Re: change in entropy when t=0k

Postby 106062642 » Sun Mar 17, 2024 9:41 pm

The entropy of a perfect crystal approaches zero as the temperature approaches absolute zero (0K), following the third law of thermodynamics. According to this law, at absolute zero temperature, the entropy of any pure, perfectly organized crystalline solid is zero.

705903057
Posts: 24
Joined: Wed Jan 17, 2024 8:26 am

Re: change in entropy when t=0k

Postby 705903057 » Mon Mar 18, 2024 11:19 am

According to the third law of thermodynamics, as the temperature of a system approaches absolute zero, the entropy of a perfect crystal also approaches zero. This is often expressed as the statement that the entropy of a perfectly ordered, pure crystalline substance at absolute zero is zero. In practical terms, calculating the change in entropy of a system at absolute zero temperature would require detailed knowledge of the system's properties, such as its specific heat capacity, molecular structure, and any other factors that may influence entropy.

Shayanel Hoque 2A
Posts: 49
Joined: Fri Sep 29, 2023 10:27 am

Re: change in entropy when t=0k

Postby Shayanel Hoque 2A » Mon Mar 18, 2024 1:17 pm

We weren't given a change in entropy for when T = 0 K. Instead, the question regarded to find just S.

As a result, we were supposed to use to Boltzmann constant for when S = kB ln W, where W is 6 (for the 6 orientations of benzene).

That gave us S for 1 mole, so we were to multiply that by Avagadro's constant to get S for the number of molecules.


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