U total - 3/2nRT

Volume:
Temperature:

Moderators: Chem_Mod, Chem_Admin

Samantha Chung 4I
Posts: 77
Joined: Wed Oct 03, 2018 12:16 am

U total - 3/2nRT

Postby Samantha Chung 4I » Tue Feb 05, 2019 12:08 am

The equation introduced today in class, U total = 3/2 nRT , I was wondering if this only applies to reversible reactions? Or does it apply to both reversible and irreversible reactions?

Saman Andalib 1H
Posts: 73
Joined: Fri Sep 28, 2018 12:16 am

Re: U total - 3/2nRT

Postby Saman Andalib 1H » Tue Feb 05, 2019 12:49 am

This equation was briefly mentioned in the derivation of the formula for the reversible, isothermic reaction formula to solve for the amount of work done by a system. The more important system to know in-depth is the work formula for a reversible reaction

w=-nRTln(Vfinal/Vinitial)

Dimitri Speron 1C
Posts: 60
Joined: Fri Sep 28, 2018 12:17 am
Been upvoted: 1 time

Re: U total - 3/2nRT

Postby Dimitri Speron 1C » Tue Feb 05, 2019 11:04 am

This equation is derived from the equipartition theorem. This is the form that is for the translational energy of a monatomic gas, and the form can change as you change the molecular structure of the gas in question. (i.e. you have diatomic or polyatomic gases) The equipartition theorem gives us the total translational energy in 3 dimensions for a single particle, and the formula given in class just extends that to the number of moles present by multiplying by n.

Lisa Werner 2F
Posts: 72
Joined: Fri Sep 28, 2018 12:17 am

Re: U total - 3/2nRT

Postby Lisa Werner 2F » Tue Feb 05, 2019 7:30 pm

Also, I believe it can only be used for ideal gases.


Return to “Entropy Changes Due to Changes in Volume and Temperature”

Who is online

Users browsing this forum: No registered users and 3 guests