Cv/Cp versus R

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chloewinnett1L
Posts: 55
Joined: Fri Sep 28, 2018 12:20 am

Cv/Cp versus R

Postby chloewinnett1L » Sat Feb 09, 2019 5:59 pm

When calculating ΔS, when should we use R and when should we use Cv and Cp, or (3/2)R and (5/2)R, respectively?

Bijan Mehdizadeh 1B
Posts: 73
Joined: Fri Sep 28, 2018 12:15 am

Re: Cv/Cp versus R

Postby Bijan Mehdizadeh 1B » Sat Feb 09, 2019 7:47 pm

It depends what values you are given and which one(s) you need to find. However, R is only used in reversible isothermal reactions while C is used when temperature is changing, and you use Cv or Cp depending on whether volume or pressure are constant.

Riley Dean 2D
Posts: 60
Joined: Fri Sep 28, 2018 12:15 am

Re: Cv/Cp versus R

Postby Riley Dean 2D » Sat Feb 09, 2019 11:06 pm

R is used for reversible reactions when temp is constant, usually like if you have deltaS=nRln(v2/v2), then use deltaS=nCvln(t2/t1) for a constant volume and a change in temp and then deltaS=nCpln(t2/t1) for a constant pressure and a change in temp

Niveda_B_3I
Posts: 60
Joined: Fri Sep 28, 2018 12:24 am

Re: Cv/Cp versus R

Postby Niveda_B_3I » Sun Feb 10, 2019 4:47 pm

Cv is for when volume is constant, and Cp is used for when pressure is constant.

Katelyn Phan 2A
Posts: 61
Joined: Fri Sep 28, 2018 12:23 am

Re: Cv/Cp versus R

Postby Katelyn Phan 2A » Mon Feb 11, 2019 9:13 am

R is used in isothermal reactions whereas 3/2R and 5/2R are used in place of Cp or Cv where there is a temperature change.


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