Page 1 of 1

Delta S equations

Posted: Wed Feb 13, 2019 12:20 pm
by Katherine Grillo 1B
I'm confused about the different delta S equations. When does delta S equal q/t vs nRln(V2/V1) vs nCln(T2/T1)?

Re: Delta S equations

Posted: Wed Feb 13, 2019 12:29 pm
by MaanasO 1A
Hi Katherine!

dS = q/t when you're dealing with a reversible process. dS = nRln(Vf/Vi) when the process is isothermal. dS = nCln(Tf/Ti) when there's a change in temperature associated with the change in entropy. Your C value will change based on whether your volume (Cv) or pressure (Cp) are constant.

Hope that helps!

Re: Delta S equations

Posted: Wed Feb 13, 2019 12:51 pm
by 705192887
MaanasO 1A wrote:Hi Katherine!

dS = q/t when you're dealing with a reversible process. dS = nRln(Vf/Vi) when the process is isothermal. dS = nCln(Tf/Ti) when there's a change in temperature associated with the change in entropy. Your C value will change based on whether your volume (Cv) or pressure (Cp) are constant.

Hope that helps!


In the last sentence you said the C value will change depending on whether volume or pressure are constant. Could you elaborate on that?

Re: Delta S equations

Posted: Wed Feb 13, 2019 1:06 pm
by Zenita Leang 2K
If you have a constant volume then you will use Cv which is equivalent to R. If it has a constant pressure, then you will use Cp which is equivalent to R. R is the constant on the constants and equations sheet.