Cp and Cv

Moderators: Chem_Mod, Chem_Admin

105907609
Posts: 93
Joined: Fri Sep 29, 2023 11:38 am

Cp and Cv

Postby 105907609 » Tue Feb 27, 2024 6:10 pm

What is the explanation for why Cp>Cv always? I'm not sure I understand why this can be the case no matter what.

William Baik DISC3B
Posts: 41
Joined: Sat Nov 11, 2023 8:26 am

Re: Cp and Cv

Postby William Baik DISC3B » Tue Feb 27, 2024 6:22 pm

Hey!
This has to do with our first law of thermodynamics, which states Internal Energy = Q + W. In constant pressure situations, the heat absorbed for an increase in internal energy has to account for the amount of work the system ends up doing as well, which means it would require more heat to increase the net internal energy (since W should be negative here). Conversely, since Cv means we are in constant volume situations, there is no work being done; therefore, less heat is needed to raise our internal energy of the system, which is usually why Cp > Cv.

Hope this helps!

Georgia Salcau 1A
Posts: 42
Joined: Fri Sep 29, 2023 9:30 am

Re: Cp and Cv

Postby Georgia Salcau 1A » Tue Feb 27, 2024 6:22 pm

cp is always greater than cv because when heat is added at constant pressure it can expand its volume whereas at constant volume the volume is constant. hope this makes sense!


Return to “Calculating Standard Reaction Entropies (e.g. , Using Standard Molar Entropies)”

Who is online

Users browsing this forum: No registered users and 2 guests