Molar entropy

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Evelyn-Marian Barber
Posts: 44
Joined: Mon Jan 09, 2023 9:48 am

Molar entropy

Postby Evelyn-Marian Barber » Wed Feb 08, 2023 8:20 pm

How do we calculate what compound will have a higher molar entropy? For example, if it is between HBr and HF, how do we know which one has a higher molar entropy?

Adam Jameel 2A
Posts: 35
Joined: Mon Jan 09, 2023 8:45 am

Re: Molar entropy

Postby Adam Jameel 2A » Thu Feb 09, 2023 11:13 am

typically as molar mass increases, molar entropy increases so in this instance, HBr being heavier than HF, typically has a higher molar entropy.

Harry Forbeck 2A
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Joined: Mon Jan 09, 2023 8:44 am

Re: Molar entropy

Postby Harry Forbeck 2A » Wed Feb 15, 2023 9:54 am

Also, another big factor in molar entropy is the complexity of the molecule, so if you have something like H vs HF, then HF would have the higher molar entropy because it is a more complex molecule.

Sydney Nguyen 1K
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Joined: Mon Jan 09, 2023 8:36 am

Re: Molar entropy

Postby Sydney Nguyen 1K » Wed Feb 15, 2023 12:19 pm

The entropy of a substance increases with its molecular weight and complexity, and with temperature. The entropy also increases as the pressure or concentration becomes smaller. Entropies of gases are much larger than those of condensed phases. In this case, the molecular weight of HBr is 80.91 g/mol and the molecular weight of HF is 20.01 g/mol. Thus, 1 mole of HBr has greater entropy.

Jessica Gebraeel 1A
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Joined: Mon Jan 09, 2023 2:22 am
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Re: Molar entropy

Postby Jessica Gebraeel 1A » Wed Feb 15, 2023 12:34 pm

The entropy of molecules with a heavier molecular weight is larger! Molar entropy also tends to increase with a decrease in pressure (which can be caused by a decrease of concentration). In your question, the answer should just be the one with a larger mass!

suhas yarra 2D
Posts: 34
Joined: Mon Jan 09, 2023 8:57 am

Re: Molar entropy

Postby suhas yarra 2D » Sat Feb 18, 2023 4:00 pm

You cannot always calculate, but predict based on factors: Molecular weight, complexity, and temperature. As these three factors increase so does the entropy. Additionally, phases matter (gas has higher entropy than liquid, then solid).

BeauBrown
Posts: 36
Joined: Mon Jan 09, 2023 8:47 am

Re: Molar entropy

Postby BeauBrown » Sat Feb 18, 2023 9:04 pm

Entropy is disorder, and the heavier the molecule the less order, meaning a higher molar mass is a higher S


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