Why is deltaG negative and spontaneous?






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LyahFitzpatrick 2E
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Why is deltaG negative and spontaneous?

Postby LyahFitzpatrick 2E » Mon Mar 14, 2022 12:13 am

If entropy and enthalpy are both spontaneous and positive values, why is deltaG spontaneous when negative?

Ashwin Vasudevan 3A
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Re: Why is deltaG negative and spontaneous?

Postby Ashwin Vasudevan 3A » Mon Mar 14, 2022 1:49 am

Reactions with a negative ∆G release energy, which means that they can proceed without an energy input (are spontaneous). In contrast, reactions with a positive ∆G need an input of energy in order to take place.

cnyland
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Re: Why is deltaG negative and spontaneous?

Postby cnyland » Mon Mar 14, 2022 10:36 am

delta G is spontaneous when negative, this was discussed during the lecture where professor lavelle derived the delta G = deltaH - TdeltaS equation!

mmcqueen
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Re: Why is deltaG negative and spontaneous?

Postby mmcqueen » Mon Mar 14, 2022 1:45 pm

The negative value refers to the fact that energy is released when deltaG is spontaneous.

705968973
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Re: Why is deltaG negative and spontaneous?

Postby 705968973 » Sat Jan 28, 2023 5:34 pm

In the case of entropy, it is spontaneous with a positive value. However, in the case of enthalpy, reactions are usually spontaneous when it is negative because exothermic reactions do not require any input of energy to get the reaction started. Delta G refers to the difference in free energy between the products and the reactants. If the difference in free energy between the products and reactants is negative, this means that the products possess less free energy than the reactants. This means that the reaction had more free energy to begin with on the reactant side which makes the reaction spontaneous. This is why reactions are spontaneous with negative delta G.


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