Gibbs and Electrochem






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Ashwin Babu 1I
Posts: 28
Joined: Fri Sep 29, 2023 10:15 am

Gibbs and Electrochem

Postby Ashwin Babu 1I » Sat Mar 16, 2024 10:18 pm

How can we use Gibbs free energy to predict the voltage of an electrochemical cell, and how does it relate to electrical work?

Ashely_Pavon_2E
Posts: 80
Joined: Fri Sep 29, 2023 11:44 am

Re: Gibbs and Electrochem

Postby Ashely_Pavon_2E » Sat Mar 16, 2024 10:22 pm

Gibbs free energy and voltage are related by the equation J/V = C, where C is coulombs. However we convert it using faraday, so we get DeltaG=-nFEcell.

vkhauv2004
Posts: 41
Joined: Tue Nov 14, 2023 8:57 am

Re: Gibbs and Electrochem

Postby vkhauv2004 » Sat Mar 16, 2024 10:24 pm

Gibbs free energy relates to the voltage or Ecell in which the equation for delta G = -nFE. If we are given the values of delta G and mols for n, we can find the value of Ecell through Ecell = - delta G/nF. As for electrical work, J/V = C which is coulombs.

Sana M 1E
Posts: 95
Joined: Fri Sep 29, 2023 12:01 pm

Re: Gibbs and Electrochem

Postby Sana M 1E » Sat Mar 16, 2024 10:24 pm

Using the formula delta G(standard) = -nFE (standard), where delta G represents the Gibbs free energy, the E represents cell potential, one can find the voltage from Gibbs free energy or vice versa. The n is the number of moles while the F is represents Faraday's constant, which is equal to 96485 Coulombs/mole.


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