Spontaneity






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josephyim1L
Posts: 61
Joined: Fri Sep 28, 2018 12:15 am

Spontaneity

Postby josephyim1L » Thu Feb 28, 2019 2:26 pm

How do I determine if a reaction is spontaneous or non spontaneous? E.g. is water melting spontaneous? How do I think through these different scenarios given?

Hovik Mike Mkryan 2I
Posts: 95
Joined: Fri Sep 28, 2018 12:25 am

Re: Spontaneity

Postby Hovik Mike Mkryan 2I » Thu Feb 28, 2019 6:09 pm

Hello,
Water melting will be spontaneous at its melting point. The scenario has to make clear under what conditions the water is present. The water melting will be spontaneous at 0 Celsius , but it won't be below that temperature. Hope this helped!

Kevin Tang 4L
Posts: 83
Joined: Fri Sep 28, 2018 12:28 am

Re: Spontaneity

Postby Kevin Tang 4L » Sat Mar 02, 2019 9:10 pm

josephyim1H wrote:How do I determine if a reaction is spontaneous or non spontaneous? E.g. is water melting spontaneous? How do I think through these different scenarios given?


Spontaneous means the Gibbs Free Energy is less than 0 and not spontaneous means Gibbs Free Energy is greater than 0. Ice will melt spontaneously, turning into a liquid when the temperature is greater than 0 degree C. Although changes in pressure change what temps it is spontaneous at though we shouldnt need to know how to apply this.

Sapna Ramappa 1J
Posts: 63
Joined: Fri Sep 28, 2018 12:24 am

Re: Spontaneity

Postby Sapna Ramappa 1J » Sat Mar 09, 2019 8:41 am

Try to look at the situations given and determine whether or not it'll happen without an input of energy.

Soumya Ravichandran 4H
Posts: 62
Joined: Fri Sep 28, 2018 12:19 am

Re: Spontaneity

Postby Soumya Ravichandran 4H » Sat Mar 09, 2019 12:14 pm

You can determine the spontaneity of a reaction by calculating delta G using standard reaction gibbs free energy values or by comparing the signs for enthalpy and entropy at fixed temperature values.


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