Entropy of universe
Moderators: Chem_Mod, Chem_Admin
-
- Posts: 111
- Joined: Wed Sep 18, 2019 12:19 am
Entropy of universe
Does anyone have an explanation on why it is a spontaneous process if the change in entropy of the universe is +? Why is this favorable.
-
- Posts: 101
- Joined: Mon Jun 17, 2019 7:24 am
Re: Entropy of universe
The universe favors disorder. The textbook has a good example: it's a lot easier for heat to leave a block of metal than enter it because in order for it to enter the block of metal, it has to be concentrated and directional.
Re: Entropy of universe
Since represents a perfectly ordered material (aka equilibrium), a positive value for S means that the system has excess energy of some sort that will dissipate through heat, work, phase change, etc.
Therefore, since the system will want to somehow decrease its energy to reach a more stable state, it will lead to a spontaneous process.
Therefore, since the system will want to somehow decrease its energy to reach a more stable state, it will lead to a spontaneous process.
-
- Posts: 102
- Joined: Fri Aug 30, 2019 12:17 am
Re: Entropy of universe
Adding on, a reaction can be spontaneous even when delta S is negative if delta H is negative enough, as long as the delta G value is negative.
delta G = delta H - T(delta S)
delta G = delta H - T(delta S)
Return to “Gibbs Free Energy Concepts and Calculations”
Who is online
Users browsing this forum: No registered users and 4 guests