Van't Hoff Equation






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AlyssaYeh_1B
Posts: 100
Joined: Sat Aug 17, 2019 12:16 am

Van't Hoff Equation

Postby AlyssaYeh_1B » Fri Feb 14, 2020 4:22 pm

The Van't Hoff equation can be used to calculate K at a different temperature, but only if delta S nought and delta H nought are assumed to be constant. Will that always be the case in reality, though? Will delta S nought and delta H nought always be constant in the problems that we're asked to do?

005324438
Posts: 51
Joined: Sat Aug 24, 2019 12:16 am

Re: Van't Hoff Equation

Postby 005324438 » Fri Feb 14, 2020 6:30 pm

I think in real life examples it isn't realistic, but if something is constant in a problem, there will be some way for you to tell, whether they tell you or they tell you something about the system that hints at it.

Alex Chen 2L
Posts: 86
Joined: Wed Sep 18, 2019 12:21 am

Re: Van't Hoff Equation

Postby Alex Chen 2L » Fri Feb 14, 2020 8:29 pm

Delta H nought and delta S nought are always constant, because they are the changes in enthalpy/entropy in constant standard conditions (25 deg C, 1 atm). Therefore the Van't Hoff equation should always be accurate as long as those two values are known.

705302428
Posts: 50
Joined: Sat Aug 24, 2019 12:16 am

Re: Van't Hoff Equation

Postby 705302428 » Fri Feb 14, 2020 9:02 pm

I think you will be told whether or not change in S is constant.


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