Calculating Gibbs Free Energy
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Calculating Gibbs Free Energy
When calculating Gibbs free energy, do you take into account stoichiometric coefficients?
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Re: Calculating Gibbs Free Energy
deltaG= -nFE: You only take into account the moles of electrons (the stoichiometric coefficient in front of the electron), because the coefficients in front of the compounds do not affect Ecell.
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Re: Calculating Gibbs Free Energy
G=H-TS
Enthalpy (H) and entropy (S) take into account stoichiometric coefficients, so I guess you could say that G requires you take into account stoichiometric coefficients. However, when calculating G in regards to electrochemistry, you do not take them into account.
Enthalpy (H) and entropy (S) take into account stoichiometric coefficients, so I guess you could say that G requires you take into account stoichiometric coefficients. However, when calculating G in regards to electrochemistry, you do not take them into account.
Re: Calculating Gibbs Free Energy
When calculating deltaG using the products minus reactants method, you would have to take into account the stoichiometric coefficients.
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Re: Calculating Gibbs Free Energy
005384106 wrote:In what situation would S(total) ever be = 0?
S can only be 0 for a molecule at 0K which is theoretically unacheivable. If is is 0 between reactants and products in a reaction, that is because they had the same entropy value with opposite signs (coincidence)
Re: Calculating Gibbs Free Energy
WGaines_2E wrote:005384106 wrote:In what situation would S(total) ever be = 0?
S can only be 0 for a molecule at 0K which is theoretically unacheivable. If is is 0 between reactants and products in a reaction, that is because they had the same entropy value with opposite signs (coincidence)
I just wanted to clarify to make sure I understood this, can reactants and products have different entropy values?
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