Van't Hoff's Equation


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Daniel Yu 1E
Posts: 100
Joined: Sat Aug 24, 2019 12:15 am

Van't Hoff's Equation

Postby Daniel Yu 1E » Sun Feb 16, 2020 9:54 pm

What is the significance of Van't Hoff's Equation?
In lecture Dr. Lavelle mentioned something about how it relates the K, chemical equilibria, to S, entropy, but how is that useful?

Alex Chen 2L
Posts: 86
Joined: Wed Sep 18, 2019 12:21 am

Re: Van't Hoff's Equation

Postby Alex Chen 2L » Sun Feb 16, 2020 10:02 pm

You might be thinking of the equation involving standard delta G's relation to the equilibrium constant K. Van't Hoff's Equation mainly relates a temperature change to its effect on K, if you already know the standard enthalpy change.

Sukanya Mohapatra 2G
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Joined: Sat Aug 17, 2019 12:18 am
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Re: Van't Hoff's Equation

Postby Sukanya Mohapatra 2G » Sun Feb 16, 2020 10:35 pm

The Van 't Hoff equation relates the change in the equilibrium constant, Keq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, ΔH for the process.

Trent Yamamoto 2J
Posts: 111
Joined: Sat Aug 17, 2019 12:18 am

Re: Van't Hoff's Equation

Postby Trent Yamamoto 2J » Sun Feb 16, 2020 10:42 pm

The Van't Hoff Equation is used to find the temperature dependence of K and can be used to calculate K at a different temperature if delta H is known. Additionally, the difference between two Van't Hoff Equations can be evaluated to find lnK2-lnK1 (given that delta s and delta h are both constant).


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