usage
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Re: usage
I know in lecture he said that it could be used for calculating k at different temperatures if standard enthalpy is known, but can anyone give some more specifics on how to find other variables with this equation?
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Re: usage
The equation
lnK=−ΔHo/RT + −ΔSo/R
can be used to find the temperature dependency of K. How K increases or decreases with temperature is linked to whether the reaction enthalpy is positive or negative.
This is because the modified version of the equation
ln(K2/K1)=−ΔHo/R(1/T2−1/T1)
can be used to find any of the missing variables in the equation. For example, if you know ΔHo, K1, T2, and T1, then you can calculate K2.
lnK=−ΔHo/RT + −ΔSo/R
can be used to find the temperature dependency of K. How K increases or decreases with temperature is linked to whether the reaction enthalpy is positive or negative.
This is because the modified version of the equation
ln(K2/K1)=−ΔHo/R(1/T2−1/T1)
can be used to find any of the missing variables in the equation. For example, if you know ΔHo, K1, T2, and T1, then you can calculate K2.
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Re: usage
The equation, when given the other components, can be used to find delta H, T, delta S, and K. In some circumstances, you can use n*delta H = q or delta G = -RTlnK in conjunction to help you.
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Re: usage
You can use it to find different components of the reaction such as delta H and K when Temperature changes.
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Re: usage
The Van't Hoff equation is typically used to calculate K at a different temperature if the change in standard enthalpy is known. However, I suppose we could also use it to calculate any of the other values in the equation if we had enough information.
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Re: usage
It is usually used to calculate K, but if given enough of the other variables in the problem you could rearrange the equation to solve for an unknown.
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