Does the order matter when we are writing the half reactions as long as we are able to cancel the number of electrons correctly?
If we are writing an oxidation half reaction, does it have to be Zn+ arrow Zn2+ + e-? or can we write it as Zn2+ + e- arrow Zn+ ?
Half Reaction Order
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Re: Half Reaction Order
The placement of the arrow indicates whether oxidation or reduction occurs, so it is important. If it is Zn2+ + 2e- --> Zn, it is reduction since the zinc cation gains electrons. If it is Zn --> Zn2+ + 2e-, it is oxidation since zinc loses electrons.
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Re: Half Reaction Order
It depends on what you are going to do with the half reactions. If you are doing it simply to determine the number of electrons being exchanged or identifying the anode and cathode while finding the standard potential, then the direction of your reactions shouldn't matter.
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Re: Half Reaction Order
Mathematically it may not matter, however, it would be more correct to keep the equations true to whether it is being reduced or oxidized. Furthermore, it would help you better keep track of what is occurring in a reaction so you can answer any concept related questions more efficiently.
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Re: Half Reaction Order
The direction does matter, as it determines what forms what in the reaction and whether it is oxidized or reduced.
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Re: Half Reaction Order
A pattern that I have noticed while doing problems is that when it is an oxidation half reaction the electrons go on the right and when we have a reduction half reaction the electrons are on the left.
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Re: Half Reaction Order
The order does matter because the placement of the electron in the half reaction determines whether it is oxidation or reduction. If writing an oxidation reaction, you would write Zn+ arrow Zn2+ + e-, which means that that electrons are being lost, since it is oxidation. If writing a reduction reaction, the electrons would go on the reactants side, since electrons are being gained in reduction.
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Re: Half Reaction Order
The oxidation half reaction includes the electrons on the right side of the arrow.
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Re: Half Reaction Order
An oxidation reaction would have the electrons added on the right side of the arrow (electrons are lost) and a reduction reaction would have electrons on the left side (electrons are gained)
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Re: Half Reaction Order
An oxidation reaction would have the electrons added (electrons are lost), so they should be on the right side of the arrow. A reduction reaction would have the opposite situation occurring, with electrons being gained so they will be listed on the left side.
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