chemical principles edition 6 problem 1.13


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Kassidy Tran 1E
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Joined: Fri Sep 28, 2018 12:15 am

chemical principles edition 6 problem 1.13

Postby Kassidy Tran 1E » Tue Oct 09, 2018 8:47 pm

I'm a bit confused on this problem:
Use the Rydberg formula for atomic hydrogen to calculate the wavelength of radiation generated by the transition from n = 4 to n = 2.
In this problem, would 4 be considered n1 and 2 be n2? Or should it be the other way around to avoid any negative values?

Mindy Kim 4C
Posts: 65
Joined: Fri Sep 28, 2018 12:25 am

Re: chemical principles edition 6 problem 1.13

Postby Mindy Kim 4C » Tue Oct 09, 2018 9:03 pm

When finding the wavelength of radiation emitted by a hydrogen atom in a transition from one energy level to another, the initial or starting energy level is n1 and the final energy level is n2. Therefore, n1=4 and n2=2. Your change in energy will end up being negative because when an electron moves to a lower energy level, it emits energy. However, when calculating wavelength, you make this value positive as the loss in energy is converted to photons. There cannot be a negative wavelength, so making the value from the Rydberg's formula positive ensures you get a positive wavelength as your final answer.


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