Help on 14.11d

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Joanna Pham - 2D
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Help on 14.11d

Postby Joanna Pham - 2D » Sun Feb 24, 2019 9:09 pm

For 14.11 part d, the question asks us to write the half reactions and the balance redox reaction for the following galvanic cell:

Pt(s) | O2 (g) | H+ (aq) || OH- (aq) | O2 (g) | Pt (g)

I understand that the side to the left of the salt bridge represents oxidation and the side to the right represents reduction, but I have no idea how to write the oxidation and reduction half reactions for this. Could someone help me please?

Thanks!

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Re: Help on 14.11d

Postby Chem_Mod » Mon Feb 25, 2019 2:55 pm

H+(aq) means there is water in the electrode. Water contains oxygen with a –2 oxidation state. Therefore, the water is being oxidized to O2(g) (oxidation state of 0). Similarly, in the other electrode, O2(g) (oxidation state 0) is being reduced to OH(aq) (oxidation state –2).


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