Standard hydrogen electrode  [ENDORSED]

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Malia Shitabata 1F
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Standard hydrogen electrode

Postby Malia Shitabata 1F » Thu Feb 20, 2020 12:19 pm

Why do we compare the electron transfer of all cells to a standard hydrogen electrode as opposed to another element electrode?

805303639
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Re: Standard hydrogen electrode

Postby 805303639 » Thu Feb 20, 2020 2:52 pm

Absolute potentials cannot be measured, so scientists need a reference electrode. The selection of hydrogen for this purpose is arbitrary. Early researchers of electrochemistry likely selected hydrogen given the relative ease of obtaining/constructing a hydrogen electrode/solution.

Chem_Mod
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Re: Standard hydrogen electrode  [ENDORSED]

Postby Chem_Mod » Thu Feb 20, 2020 2:53 pm

A common reference is needed.
For the same reasons we use sea level as a common reference point for altitude.

The standard hydrogen electrode uses a simple and common reaction: 2 H+(aq) + 2 e− → H2(g)

Edmund Zhi 2B
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Joined: Sat Jul 20, 2019 12:16 am

Re: Standard hydrogen electrode

Postby Edmund Zhi 2B » Fri Feb 21, 2020 1:35 am

So then are values of E just relative to the value determined by the half reaction involving hydrogen?


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