6M.1

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JamieVu_2C
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Joined: Thu Jul 25, 2019 12:16 am

6M.1

Postby JamieVu_2C » Mon Feb 24, 2020 4:25 pm

A student was given a standard Cu(s)|Cu2+(aq) half-cell and another half-cell containing an unknown metal M in 1.00M M(NO3)2(aq) and formed the cell M(s)|M+(aq)||Cu2+(aq)|Cu(s). The cell potential was found to be -0.689 V. What is the value of E(M2+/M)?

In this problem, since Cu2+(aq)/Cu(s) is written on the right side of the cell diagram, it should be the cathode. So, Cu2+(aq)/Cu(s) should be written as a reduction half reaction. However, the textbook solutions says that it is the anode and is instead written as an oxidation half reaction. Why is this? If the Cu2+(aq)/Cu(s) electrode is on the right of the cell diagram, then shouldn't it be the cathode?

Brian Tangsombatvisit 1C
Posts: 119
Joined: Sat Aug 17, 2019 12:15 am

Re: 6M.1

Postby Brian Tangsombatvisit 1C » Mon Feb 24, 2020 5:11 pm

You're right, if the Cu half reaction is written on the right side of the equation, it should be the cathode. This is probably a typo in the textbook as the solutions manual writes it on the left side of the cell diagram, making it the anode.

Jessica Esparza 2H
Posts: 130
Joined: Wed Sep 18, 2019 12:15 am

Re: 6M.1

Postby Jessica Esparza 2H » Tue Feb 25, 2020 10:57 am

Has anyone confirmed if this is a typo? I was confused when looking at the answer key.

Alexis Webb 2B
Posts: 124
Joined: Thu Jul 11, 2019 12:15 am

Re: 6M.1

Postby Alexis Webb 2B » Tue Feb 25, 2020 4:12 pm

I am not sure if it is a typo, but I was wondering what answer would you get if the Cu2+/Cu is the cathode so that I can check mine.

Daniel Honeychurch1C
Posts: 109
Joined: Thu Jul 11, 2019 12:15 am

Re: 6M.1

Postby Daniel Honeychurch1C » Tue Feb 25, 2020 4:29 pm

In 6 L.3 of the textbook, it says that a positive cell potential indicates that the right side of the cell diagram is the cathode. Conversely, a negative cell potential indicates that the left side of the cell diagram in the cathode. In this question, the cell potential is negative (-0.689 V), so the left side of the cell diagram (M 2+/M) is the cathode.


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