Sapling Week 7/8 question 15


Moderators: Chem_Mod, Chem_Admin

Pratika Nagpal
Posts: 48
Joined: Wed Feb 19, 2020 12:20 am

Sapling Week 7/8 question 15

Postby Pratika Nagpal » Sun Feb 28, 2021 9:03 pm

Can someone help me with the steps to solve this.
Attachments
Screenshot 2021-02-28 at 9.00.19 PM.png

Sana Nagori 2H
Posts: 149
Joined: Wed Sep 30, 2020 9:43 pm
Been upvoted: 1 time

Re: Sapling Week 7/8 question 15

Postby Sana Nagori 2H » Sun Feb 28, 2021 9:08 pm

I think you use Nernst equation. So you need to find the Enaught and then plug everything in to the equation. For Q you would do .761 on top and then .01 in the denominator.

Nathan Lao 2I
Posts: 100
Joined: Wed Sep 30, 2020 9:40 pm
Been upvoted: 1 time

Re: Sapling Week 7/8 question 15

Postby Nathan Lao 2I » Sun Feb 28, 2021 9:08 pm

This problem involves the Nernst equation. The first step is to find the standard reduction potential of this cell. Then, using the given concentrations, we can solve for Q and plug everything else(such as temp, R, F, etc) into the equation. It''s important to note that the variable n in the question is based on moles of electrons transferred in the equation we get from the standard reduction potential table too.

Joseph Hsing 2C
Posts: 99
Joined: Wed Sep 30, 2020 9:42 pm

Re: Sapling Week 7/8 question 15

Postby Joseph Hsing 2C » Sun Feb 28, 2021 9:09 pm

Use the Nernst equation to find the cell potential. E = E naught - RT/nF lnQ. Separate the two half-reactions with the reduction half at the cathode and oxidation half at the anode.

Look up standard reduction potential values and plug into E= E cathode - E anode. (No need to change given signs here)

2 moles of electrons are transferred per mole of reaction when we balanced the half reactions so n=2.

Find Q, convert temp to Kelvins, and lastly plug in all the calculated values and constants into the Nernst equation to find E.

I hope this helped!

Sara_Lim_2C
Posts: 106
Joined: Wed Sep 30, 2020 9:55 pm

Re: Sapling Week 7/8 question 15

Postby Sara_Lim_2C » Sun Feb 28, 2021 9:10 pm

I solved this by using this version of the Nernst Equation: E= (E naught) - (0.05916V/n)log(Q). Use the standard reductions table to find E naught of the half reactions, and use those to find the E naught the whole reaction. Then use the two concentrations to find Q, which is [Cr2+]/[Fe2+]. n is the number of moles of electrons transferred. We can see in the reaction that 2 moles of electrons are transferred. So then you plug in all those numbers to find E. Hope that helps!

Natalie 3k
Posts: 102
Joined: Wed Sep 30, 2020 10:11 pm

Re: Sapling Week 7/8 question 15

Postby Natalie 3k » Sun Feb 28, 2021 9:12 pm

First you have to find E°cell using the table (Ecathode-Eanode), and with that value you have to use the Nernst equation and plug in the values and that should give you the answer

Pratika Nagpal
Posts: 48
Joined: Wed Feb 19, 2020 12:20 am

Re: Sapling Week 7/8 question 15

Postby Pratika Nagpal » Sun Feb 28, 2021 9:30 pm

All of these responses are super helpful. Thank you !


Return to “Work, Gibbs Free Energy, Cell (Redox) Potentials”

Who is online

Users browsing this forum: No registered users and 9 guests