Textbook 6.65


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ChihWei Chen 2C
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Joined: Wed Nov 18, 2020 12:24 am

Textbook 6.65

Postby ChihWei Chen 2C » Fri Mar 12, 2021 11:22 pm

What range (in volts) does a voltmeter need to have to measure pH in the range of 1 to 14 at 25 °C if the voltage is zero when pH = 7?

Can anyone explain how to approach this problem? I understand why in the solution they used the equation Enaught = RT/nF ln K, but why did they set K = [H+]/[OH-]? Where in the problem does it imply that?

Savana Maxfield 3F
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Joined: Wed Sep 30, 2020 10:00 pm

Re: Textbook 6.65

Postby Savana Maxfield 3F » Fri Mar 12, 2021 11:45 pm

I think they set K=[H+]/[OH-] because when the pH is equal to 7, both [H+] and [OH-] are equal to 1.0x10^7M

ChihWei Chen 2C
Posts: 58
Joined: Wed Nov 18, 2020 12:24 am

Re: Textbook 6.65

Postby ChihWei Chen 2C » Fri Mar 12, 2021 11:53 pm

Savana Maxfield 3F wrote:I think they set K=[H+]/[OH-] because when the pH is equal to 7, both [H+] and [OH-] are equal to 1.0x10^7M


Why couldn't it be [OH-]/[H+] though?

Savana Maxfield 3F
Posts: 199
Joined: Wed Sep 30, 2020 10:00 pm

Re: Textbook 6.65

Postby Savana Maxfield 3F » Sat Mar 13, 2021 12:01 am

I don't think so... This is what the solutions manual says:
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