Standard Cell Potential and K


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alexia11
Posts: 86
Joined: Fri Sep 29, 2023 11:47 am

Standard Cell Potential and K

Postby alexia11 » Fri Mar 15, 2024 10:41 pm

What does the standard potential of a cell tell us about the value of K. Specifically, how does this relate to the Nernst equation. If a standard value is positive what does that mean for the value of k of a reaction?

Gabriel Barcelona 2L
Posts: 43
Joined: Fri Sep 29, 2023 9:58 am

Re: Standard Cell Potential and K

Postby Gabriel Barcelona 2L » Fri Mar 15, 2024 10:44 pm

A positive standard potential (E) indicates that the reaction is spontaneous in the forward direction at standard conditions and this corresponds to a value of K greater than 1. The Nernst equation allows us to relate K to E and calculate the cell potential under non-standard conditions.

Ashley Barrera 1J
Posts: 38
Joined: Tue Nov 14, 2023 9:04 am

Re: Standard Cell Potential and K

Postby Ashley Barrera 1J » Fri Mar 15, 2024 10:45 pm

The value of K, positive or negtaive determine the sign of the cell potential as well as if it is a spontaneous reaction or not?

Emily Do 1F
Posts: 43
Joined: Fri Sep 29, 2023 9:43 am

Re: Standard Cell Potential and K

Postby Emily Do 1F » Fri Mar 15, 2024 10:53 pm

Hi!

E∘ = (RT)/(nF) * ln(K)

If E∘ is positive, that means that the reaction will be spontaneous in the forward direction. To agree with the positive term, K must be > 1, as ln of anything less than 1 will yield a negative number.

006033476
Posts: 82
Joined: Fri Oct 13, 2023 8:21 am

Re: Standard Cell Potential and K

Postby 006033476 » Sun Mar 17, 2024 2:14 pm

If the Ecell is positive k will be greater than 1.


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