Why is E Standard=0 in a concentration cell?
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Re: Why is E Standard=0 in a concentration cell?
In a concentration cell, essentially the reduction half reaction and oxidation half reaction cancel each other out because the same type of solution is used in both compartments of the cell.
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Re: Why is E Standard=0 in a concentration cell?
When finding Estandard, you usually take Estandard(cathode) - Estandard(anode), but in a concentration cell, because the two reactions are the reverse of each other, their Estandard values cancel out, so you get Estandard(cathode) - Estandard(anode) = 0 = Estandard.
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Re: Why is E Standard=0 in a concentration cell?
E standard = 0 in a concentration cell since you're essentially dealing with the same reaction occurring in both directions. The E standard of the reduction half-reaction is just the negative value of the E standard of the oxidation half-reaction, and so when you add them together, you get that the total voltage is just 0.
Re: Why is E Standard=0 in a concentration cell?
At standard conditions, each compartment of the cell will be 1M. Assuming that a concentration cell uses the same solutions, then the potential difference at standard conditions is 0.
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