different units
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Re: different units
Each different ordered reactions involve having the concentrations be increased to certain powers. ^2 for second order. Therefore the units are changed by that order as well.
Re: different units
It is because you want the right units in the end when you multiply everything to find the rate using the differential or integrative rate law. In a reaction with an overall order of 4 for example, you will have the unit of mol/L multiplied by itself 4 times, so the units of k must be different so that the rate is in moles per liter per second.
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Re: different units
The units of k specifically in different order reactions are
zero-order M/s
first-order 1/s
second-order 1/M*s
zero-order M/s
first-order 1/s
second-order 1/M*s
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