15.23 b
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Re: 15.23 b
I used the equation and got the same answer as the solutions manual. I think the two equations are equivalent because of the negative sign I used in my answer, when transferred to the other side, would flip the two concentrations.
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Re: 15.23 b
It's just algebraic manipulation; flipping the numerator and denominator will give you the negative log value.
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Re: 15.23 b
If you make both sides of the equation ln([A]t/[A]0) = -kt negative, you will have: ln([A]0/[A]t) = kt. Making the natural log negative flips the content because:
ln([A]t/[A]0) = ln[A]t - ln[A]0
ln([A]t/[A]0) = ln[A]t - ln[A]0
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