Units for k


Moderators: Chem_Mod, Chem_Admin

VanessaZhu2L
Posts: 100
Joined: Wed Sep 30, 2020 9:44 pm

Units for k

Postby VanessaZhu2L » Sat Mar 13, 2021 1:19 pm

Can someone explain how to find the units of k? Does each order always have the same units or do we need to calculate it for each problem? Thank you!

JonathanM
Posts: 45
Joined: Wed Sep 30, 2020 9:31 pm

Re: Units for k

Postby JonathanM » Sat Mar 13, 2021 2:26 pm

So each order of reaction has the same units of k because the end units must always come out to M/s. So for example for a zero order reaction, the units are M/s since nothing else is multiplying k. For first order reactions the units of k are 1/s since a concentration is being multiplied in once, so in the end you get M/s. For second order reactions the units are 1/(s*M) since there are two concentrations being multiplied by K. This logic continues for any order reaction.

connie ma 3G
Posts: 104
Joined: Wed Sep 30, 2020 9:38 pm
Been upvoted: 2 times

Re: Units for k

Postby connie ma 3G » Sat Mar 13, 2021 2:34 pm

basically the units for k must ensure that the units for the resulting rate is always M/s. so if it is zero order overall then the units for k have to be M/s because rate=k. if it is first order then the units for k will be 1/s because rate=k[A] where [A] already has units of M so k only needs to add the 1/s for the units of rate to be M/s when multiplied.

RylanPurificacion 3J
Posts: 51
Joined: Mon Jan 04, 2021 12:09 pm

Re: Units for k

Postby RylanPurificacion 3J » Sat Mar 13, 2021 4:04 pm

If you wanted a equation for it, the units would be in 1/(Mz-1*s), where z is the order for the reaction.

derickngo3d
Posts: 111
Joined: Wed Sep 30, 2020 9:51 pm

Re: Units for k

Postby derickngo3d » Sat Mar 13, 2021 4:40 pm

Units for the rate constant should cancel with the units of molarity, so that the rate constant is in molar per second.
Hope this helps!

derickngo3d
Posts: 111
Joined: Wed Sep 30, 2020 9:51 pm

Re: Units for k

Postby derickngo3d » Sat Mar 13, 2021 4:59 pm

You can either memorize or just mathematically calculate the units too!
Hope this helps!

Joyce Pang 2H
Posts: 77
Joined: Wed Sep 30, 2020 9:59 pm

Re: Units for k

Postby Joyce Pang 2H » Sat Mar 13, 2021 5:07 pm

you could always just set up the equation for rate, but in units instead-- so since rate is M/s, and equation for first order would be M/s=k*M, and solving for k would leaev you with 1/s=k, etc. etc.

RyanKopeikin_2I
Posts: 81
Joined: Fri Aug 30, 2019 12:17 am

Re: Units for k

Postby RyanKopeikin_2I » Mon Mar 15, 2021 11:27 pm

To be honest I just look at the right side of the equation and figure out how to make it match the left side of the equation, which is usually in units of M/s. So if it's a second order rxn, you have M/s = k (M)(M) so you can kinda figure out that the units of k need to be M^-1•s^-1

rhettfarmer-3H
Posts: 122
Joined: Wed Sep 30, 2020 9:59 pm

Re: Units for k

Postby rhettfarmer-3H » Tue Mar 16, 2021 12:41 am

I think Mathew gave us the cheat code for K units. So rate = k a to a power. So Zero is m/s. One is 1/s and second is 1/sm.

Armen_Isayan_2L
Posts: 116
Joined: Wed Sep 30, 2020 10:09 pm

Re: Units for k

Postby Armen_Isayan_2L » Tue Mar 16, 2021 1:49 am

Hello! In order to find the units of k, you must consider that each order of reaction contains the same units of k. This is because the unit utilized in the end must be M/s. For instance, in a zero-order reaction the ultimate unit would be M/s, and this is due to the fact that no other units are multiplied to k. Also, for first-order reactions, the unit of k would be 1/s, and this is because it is being multiplied. Finally, in a second-order reaction, the unit of k is 1/(M*s), because there are two concentrations being multiplied to k.

Shana Patel 1C
Posts: 111
Joined: Wed Sep 30, 2020 9:36 pm

Re: Units for k

Postby Shana Patel 1C » Tue Mar 16, 2021 2:00 am

You can memorize or calculate it.
Rate = k a to a power. So Zero is m/s. One is 1/s and second is 1/sm.

Alan Nguyen 2I
Posts: 100
Joined: Fri Sep 24, 2021 6:43 am

Re: Units for k

Postby Alan Nguyen 2I » Sat Feb 26, 2022 5:43 pm

The units for K depend on the order of the reaction. This can be determined by keeping in mind that the rate is given in M/s. Use this to think about what units the existing terms on the other side of the equation have, and then think about cancelling units to find out what the units for K are.


Return to “General Rate Laws”

Who is online

Users browsing this forum: No registered users and 7 guests