Not zero, first, or second?


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charlottesmith3f
Posts: 22
Joined: Fri Sep 25, 2015 3:00 am

Not zero, first, or second?

Postby charlottesmith3f » Sat Feb 20, 2016 2:24 pm

What happens if we have a problem in which the rate is multiplied by two but the concentration is multiplied by four?
Is there such thing as not a zero, first, or second order, but, maybe, a half-order reaction or something?

GunvantChaudhari 2F
Posts: 25
Joined: Fri Sep 25, 2015 3:00 am

Re: Not zero, first, or second?

Postby GunvantChaudhari 2F » Sat Feb 20, 2016 2:57 pm

Yes there is such a thing as a half order reaction. For examples of how a reaction mechanism would lead to a half order reaction, see examples 2 and 3 here: http://www.science.uwaterloo.ca/~cchieh/cact/c123/ratemech.html

Matt Villanueva 3H
Posts: 11
Joined: Fri Sep 25, 2015 3:00 am

Re: Not zero, first, or second?

Postby Matt Villanueva 3H » Sat Feb 20, 2016 5:41 pm

If the rate doubles but the concentration quadrupled, then yes, the order with respect to that reactant would be a half order.

Alex Yee - 4I
Posts: 15
Joined: Wed Sep 21, 2016 2:57 pm

Re: Not zero, first, or second?

Postby Alex Yee - 4I » Sun Feb 12, 2017 2:16 am

Is there any limit to what the order of a reaction can be? Could you (theoretically) have a reaction of pi order or 2/7 order, or is it just whole numbers and their inverses?

GregoryPolyakov_1H
Posts: 16
Joined: Wed Sep 21, 2016 2:56 pm

Re: Not zero, first, or second?

Postby GregoryPolyakov_1H » Sun Feb 12, 2017 10:05 am

Do we need to be familiar with half order reactions?


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