Identifying Zero vs. First vs. Second Order Reactions
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Identifying Zero vs. First vs. Second Order Reactions
How can you identify zero, first, and second order reactions?
Re: Identifying Zero vs. First vs. Second Order Reactions
If given their graphs, you can see which graph provides a straight line based on the axes (ln [A] vs
vs [A]). If given their rate laws or chemical equations, you can see how many molecules are involved in each reaction (molecularity).
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Re: Identifying Zero vs. First vs. Second Order Reactions
In zeroth order, rate is independent of concentration of reactant so long as it is present in some quantity, in first rate is linearly dependent etc.
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Re: Identifying Zero vs. First vs. Second Order Reactions
You can do so by looking at the graphs produced by modeling the system as 0th, 1st or 2nd order. Which ever order produces a straight line is the correct order.
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Re: Identifying Zero vs. First vs. Second Order Reactions
If you are given rate constants, you can also figure out whether a reaction is zero, first, or second order:
zero order: k = M/time
first order: 1/time
second order: 1/ (M * time)
zero order: k = M/time
first order: 1/time
second order: 1/ (M * time)
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Re: Identifying Zero vs. First vs. Second Order Reactions
Also, if you are given various rates provided reactant concentrations, and rate does not change as a reactant concentration is increased or decreased, you know it is zeroth order. If it changes proportionately, it is first. If it changes exponentially, it is second or third or above.
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Re: Identifying Zero vs. First vs. Second Order Reactions
once you start becoming more comfortable with the problems you will notice trends that allow you to determine the reaction order
Re: Identifying Zero vs. First vs. Second Order Reactions
In a first order reaction, the rate of reaction is directly proportional to the concentration of a single reacting substance. Whereas in a 2nd order reaction the rate depends on the concentration of 2 reacting first order substances or a single reactant with a squared concentration. Because it depends on a single substance, the graph of a first order reaction is a straight line. For a zeroth order reaction the rate is solely dependent on the rate constant.
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