Half life


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Fdonovan 3D
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Half life

Postby Fdonovan 3D » Mon Mar 16, 2020 12:21 am

How do you calculate the half life of a zero order rxn?

Matthew Chan 1B
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Re: Half life

Postby Matthew Chan 1B » Mon Mar 16, 2020 2:15 am

t1/2=[A]0/2k

My-Lan Le 1L
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Re: Half life

Postby My-Lan Le 1L » Wed Mar 03, 2021 12:34 pm

You would use this equation for half life: t1/2=[A]0/2k. But what this equation is saying is that a half life zero order reaction is dependent on the initial concentration of A.

Emmeline Phu 1G
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Re: Half life

Postby Emmeline Phu 1G » Wed Mar 03, 2021 12:41 pm

Hi! As mentioned in lecture today, you would solve for the half life of a zero order reaction by using the equation t1/2= [A]0/ 2K. This half life equation indicates that the half life is dependent on the initial concentration of the reactant, [A]0, since k which represents the maximum rate of the enzyme/catalyst is held constant. Hope this helps! :)

Muskaan Abdul-Sattar
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Re: Half life

Postby Muskaan Abdul-Sattar » Thu Mar 04, 2021 3:49 pm

The equation for half-life, as mentioned in the lecture, would be t1/2=[A]0/2k!

KhanTran3K
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Re: Half life

Postby KhanTran3K » Thu Mar 04, 2021 5:19 pm

To calculate a half-life for a zero order reaction, the equation would be t(1/2)=[A]0/2k. In lecture yesterday, he derived this from the integrated rate law for zero order. It is important to note that the half life zero order rate depends on the concentration of [A] initial.

Annie Liang 3D
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Re: Half life

Postby Annie Liang 3D » Thu Mar 04, 2021 7:27 pm

The half life would be t1/2=[A]0/2k

Darlene Lien 3E
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Re: Half life

Postby Darlene Lien 3E » Thu Mar 04, 2021 8:21 pm

The half-life of a zero-order reaction is t1/2=[A]0/2k. This is also in Wednesday's lecture (Lecture 23). Hope this helps!

Gigi Elizarraras 2C
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Re: Half life

Postby Gigi Elizarraras 2C » Thu Mar 04, 2021 8:22 pm

To calc the half life use the equation t1/2=[A]0/2k. but you must know the INITIAL concentration:) hope this helps!

Sophia Kalanski 1A
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Re: Half life

Postby Sophia Kalanski 1A » Sat Mar 06, 2021 6:41 pm

[A]o/2K =t(1/2) is the equation and this shows that the half life of a zero order reaction is dependent on the initial concentration of A

Alexandra Ahlschlager 1L
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Re: Half life

Postby Alexandra Ahlschlager 1L » Sat Mar 06, 2021 6:48 pm

To calculate half life of a zero order reaction, you would use the equation: t1/2 = [A0] / 2k where A0 is the initial concentration and k is the rate constant.

Arnav Saud 2C
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Re: Half life

Postby Arnav Saud 2C » Sat Mar 06, 2021 7:08 pm

In order to calculate half life of a zero order reaction, you would want to use the t1/2 = [A]0/2k.

Justin Nguyen 3E
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Re: Half life

Postby Justin Nguyen 3E » Sat Mar 06, 2021 9:04 pm

You find the half-life of a zero order equation you would use t1/2=[A]0/2k and the half life of a reactant decreases as its concentration decreases

Nathan Chu 3H
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Re: Half life

Postby Nathan Chu 3H » Sat Mar 06, 2021 9:05 pm

To calculate the half-life of a zero order reaction, use the equation t1/2=[A]0/2k

Rob Tsai 2F
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Re: Half life

Postby Rob Tsai 2F » Sun Mar 07, 2021 1:09 am

You use the equation t1/2 = [A]0/2k, with [A]0 being the initial concentration of the reaction and k being the reaction rate constant.

This is derived from the zero order integrated rate law, where [A] = -kt + [A]0. The derivation is as follows:

[A] = -kt + [A]0
(1/2)[A]0 = -k(t1/2) + [A]0 (At t1/2, [A] = (1/2)[A]0) or (At the half life of the reaction, the concentration of the reactant should be half the initial)
-(1/2)[A]0 = -k(t1/2) (Combine like terms)
t1/2 = [A]0/2k (Solve for t1/2)

Hope this helps!

Taylor Newville 1C
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Re: Half life

Postby Taylor Newville 1C » Sun Mar 07, 2021 1:54 am

The half life for a zero order reaction is calculated by dividing the initial concentration of the reactant by 2 times the rate constant.
t1/2=[A]0/2k

Bella Wachter 1A
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Re: Half life

Postby Bella Wachter 1A » Sun Mar 07, 2021 2:57 pm

You would use the equation t1/2 = [A]0 / 2k

This reaction indicates that the larger the rate constant (k) gets, the shorter the half-life becomes. This makes sense because the larger the rate constant, the faster the reaction occurs, meaning it takes less time for the reactant concentration to decrease to half its original molarity.

This reaction also indicates that the half-life of a zero order reaction depends on the initial concentration of the reactant.

Grecia Velasco 1G
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Re: Half life

Postby Grecia Velasco 1G » Sun Mar 07, 2021 2:59 pm

Fdonovan 3D wrote:How do you calculate the half life of a zero order rxn?

Dr. Lavelle gave us the equation in class. It is t1/2=[A]0/2k for the half life of a zero order rxn.

Kiana Tashakori 1D
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Re: Half life

Postby Kiana Tashakori 1D » Sun Mar 07, 2021 3:25 pm

Hi! You would just use the equation t1/2= [A]0/2K to calculate the half life of a zero order reaction.

Justin Lin 1B
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Re: Half life

Postby Justin Lin 1B » Sun Mar 07, 2021 3:38 pm

We would use the equation t1/2 = [A]o / 2k. This is also in our constants and formula sheet

Chinyere Okeke 2J
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Re: Half life

Postby Chinyere Okeke 2J » Sun Mar 07, 2021 4:05 pm

To calculate the half-life of a zero-order reaction we use the equation: t1/2=[A]0/2k.

So in order to calculate it, we need to know the initial concentration of the reactant and the rate constant of the reaction. And I assume we might not know if a reaction is zero-order so we would need to be able to determine the order of the reaction given experimental data.


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