First Order Integrated Rate Laws


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Amy Luu 2G
Posts: 105
Joined: Wed Sep 18, 2019 12:19 am

First Order Integrated Rate Laws

Postby Amy Luu 2G » Sat Mar 07, 2020 6:54 pm

When the problem asks for the time it takes for a reaction to decay why do we use the equation t= (1/kr)*ln([A]0/[A]t)? Isnt there supposed to be a negative sign if we solve for t using ln([A]0/[A]t)= -krt?

Justin Seok 2A
Posts: 104
Joined: Sat Aug 24, 2019 12:15 am

Re: First Order Integrated Rate Laws

Postby Justin Seok 2A » Sat Mar 07, 2020 7:20 pm

I believe it may be the way that ln works with negatives, since -ln([A]t/[A]0) would be equivalent to ln([A]0/[A]t). So the equation would go from [A]t=[A]0*(e^(-kt)) to [A]t/[A]0 = e^-kt to ln([A]t/[A]0) = -kt to t = ln([A]0/[A]t)/k.


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