Second order
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Re: Second order
I think it's because when you're plotting 1 and 0 order reactions over time, its in terms of the reactant so it decreases over time. Second order plots are the inverse of the concentration though, so a smaller concentration leads to a bigger value for 1/A. This makes the slope positive.
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Re: Second order
The positive slope is there because it is plotting 1/[A], rather than plotting [A] like in zero order where you then see the concentration decrease.
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Re: Second order
The graph is plotting 1/concentration vs time and as time increases, the concentration of a reactant will decrease. Since the y axis is 1/concentration, the y value will increase as time goes on because concentration is in the denominator
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Re: Second order
As time goes on, the concentration of the reactant decreases. Therefore, since the second order graph plots 1/[A] over time, the denominator [A] will decrease. As the denominator of a fraction decreases, its value increases, hence the positive slope.
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Re: Second order
You plot 1/[A] on the y-axis. Since the concentration of A decreases as time goes on, the denominator of this fraction also decreases, which makes the fraction as a whole bigger.
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