Second order


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rhettfarmer-3H
Posts: 122
Joined: Wed Sep 30, 2020 9:59 pm

Second order

Postby rhettfarmer-3H » Sun Mar 14, 2021 5:17 pm

How come second order has a positive slope unlike first and zero?

SavannahScriven_1F
Posts: 107
Joined: Wed Sep 30, 2020 9:37 pm

Re: Second order

Postby SavannahScriven_1F » Sun Mar 14, 2021 5:23 pm

I think it's because when you're plotting 1 and 0 order reactions over time, its in terms of the reactant so it decreases over time. Second order plots are the inverse of the concentration though, so a smaller concentration leads to a bigger value for 1/A. This makes the slope positive.

Jessica Katz
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Re: Second order

Postby Jessica Katz » Sun Mar 14, 2021 6:19 pm

The positive slope is there because it is plotting 1/[A], rather than plotting [A] like in zero order where you then see the concentration decrease.

Valerie Tran 2B
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Re: Second order

Postby Valerie Tran 2B » Sun Mar 14, 2021 6:32 pm

The graph is plotting 1/concentration vs time and as time increases, the concentration of a reactant will decrease. Since the y axis is 1/concentration, the y value will increase as time goes on because concentration is in the denominator

Nathan Tong 3G
Posts: 101
Joined: Wed Sep 30, 2020 9:49 pm

Re: Second order

Postby Nathan Tong 3G » Mon Mar 15, 2021 12:05 pm

As time goes on, the concentration of the reactant decreases. Therefore, since the second order graph plots 1/[A] over time, the denominator [A] will decrease. As the denominator of a fraction decreases, its value increases, hence the positive slope.

Audrey Banzali-Marks 1A
Posts: 108
Joined: Fri Sep 24, 2021 6:32 am

Re: Second order

Postby Audrey Banzali-Marks 1A » Mon Feb 28, 2022 10:37 pm

You plot 1/[A] on the y-axis. Since the concentration of A decreases as time goes on, the denominator of this fraction also decreases, which makes the fraction as a whole bigger.


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