Pre-Equilibrium


Moderators: Chem_Mod, Chem_Admin

Tanner Baroni 3I
Posts: 17
Joined: Wed Sep 21, 2016 2:56 pm

Pre-Equilibrium

Postby Tanner Baroni 3I » Wed Feb 22, 2017 9:57 pm

How do we use the pre-equilibrium approach to figure out the rate law?

breinhardt3G
Posts: 10
Joined: Wed Sep 21, 2016 2:56 pm

Re: Pre-Equilibrium

Postby breinhardt3G » Wed Feb 22, 2017 10:13 pm

Basically, when the slow step involves an intermediate you use the fast step to solve for the concentration of that intermediate and use that substitution to write the rate law of the overall reaction. You can look at the example in the course reader for reference, but try looking at is as a substitution to make it easier.

Myra_Zhan_2N
Posts: 25
Joined: Fri Jul 22, 2016 3:00 am

Re: Pre-Equilibrium

Postby Myra_Zhan_2N » Wed Feb 22, 2017 11:34 pm

You know you would have to use the pre-equilibrium approach when Step 1 is fast and Step 2 is slow. This is because the intermediate will be included in the rate law equation. That is not allowed so you would need to use substitution to replace the intermediate concentration.


Return to “Reaction Mechanisms, Reaction Profiles”

Who is online

Users browsing this forum: No registered users and 1 guest