HW#15.87


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Peter Dis1G
Posts: 97
Joined: Fri Sep 29, 2017 7:04 am

HW#15.87

Postby Peter Dis1G » Tue Mar 13, 2018 2:47 pm

Don't get what the question is asking. I only know that the slow step determines the reaction rate.

Anna Goldberg 2I
Posts: 59
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Re: HW#15.87

Postby Anna Goldberg 2I » Tue Mar 13, 2018 8:12 pm

15.87 asks what conditions can be used to distinguish the two mechanisms-essentially, what mechanisms can be used to distinguish the two slow steps.
If the reaction is carried out in a highly concentrated solution of sucrose, mechanism ii will behave as a pseudo-first order reaction, due to its dependence on water. Mechanism i will occur at a rate independent of water and completely dependent on sucrose.
If the reaction is carried out in a very diluted solution, you will be unable to distinguish between the two mechanisms, as mechanism ii will behave as a pseudo-first order reaction with dependence solely on sucrose, and the concentration of water won't change.
This question revolves around the concept of pseudo-first order reactions and the consequences of having one reactant at a very high concentration.

Nickolas Manipud 1C
Posts: 60
Joined: Fri Sep 29, 2017 7:07 am

Re: HW#15.87

Postby Nickolas Manipud 1C » Wed Mar 14, 2018 10:17 pm

How do we know that ii) at high sucrose concentration is first order?


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