I'm a little confused on the definition of molecularity. Or I suppose, the definition of "species"
Is a species a single molecule, or is it a single type of molecule? I may be confused because in biology, a species is a type of organism, but this definition seems to have little to do with that. In an elementary step in which two NO molecules collide, is that one or two species?
Molecularity
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Re: Molecularity
Molecularity accounts for both the number of different types of species as well as their stoichiometric coefficients. For instance, if an elementary step had something like: 2A + B --> something, the molecularity is termolecular, because in total, there are three molecules involved.
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Re: Molecularity
A species in this case refers to the number of reactants. In the example you gave, this is bimolecular. The number of moles of reactants determines the molecularity.
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Re: Molecularity
The textbook defines molecularity as the number of reactant moles, atoms, or ions taking part in a specified elementary reaction.
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Re: Molecularity
Molecularity would be the number of molecules or species in an elementary step, and also determine the rate. Rate law for each elementary steps comes directly from molecularity.
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