Collision Model vs Activated Complex Model

Arrhenius Equation:

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jessicaosuna_1F
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Joined: Wed Sep 30, 2020 9:51 pm

Collision Model vs Activated Complex Model

Postby jessicaosuna_1F » Sat Mar 13, 2021 8:15 pm

Hi! Can somebody please explain the difference between these 2 models. Thank you :)

Andreas Krumbein 1L
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Re: Collision Model vs Activated Complex Model

Postby Andreas Krumbein 1L » Sun Mar 14, 2021 7:39 am

An activated complex consists of two molecules that are in a "transition state" meaning they can continue to form a new molecule or they can break apart again. Whether they form a new product or not depends on the amount of energy accumulated from their collision (if it's at least equal to Ea). Collision theory is similar in that the minimum kinetic energy required for a reaction to occur is equal to Ea.

Katherine_Douglas_1F
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Re: Collision Model vs Activated Complex Model

Postby Katherine_Douglas_1F » Mon Mar 15, 2021 10:24 pm

These are two different ways of looking at how activation energy is determined. In the collision model, activation energy is related to the amount of energy that needs to be transferred within a collision in order for the reaction to occur. Activated complex model instead compares an intermediate (the activated complex) to the reactants and the activation energy is the difference between the two.


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