Frequency Factor

Arrhenius Equation:

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Rayna Irving 2C
Posts: 103
Joined: Wed Sep 30, 2020 9:33 pm

Frequency Factor

Postby Rayna Irving 2C » Sun Mar 14, 2021 1:02 am

Can you do anything to affect the frequency factor in the Arrhenius Equation of a reaction (like increase the in temperature), or is it just seen as specific to each reaction?

Jessie Hsu 1C
Posts: 101
Joined: Wed Sep 30, 2020 9:49 pm

Re: Frequency Factor

Postby Jessie Hsu 1C » Sun Mar 14, 2021 1:18 am

According to this website: https://chem.libretexts.org/Bookshelves ... _Chemistry)/Kinetics/06%3A_Modeling_Reaction_Kinetics/6.02%3A_Temperature_Dependence_of_Reaction_Rates/6.2.03%3A_The_Arrhenius_Law/6.2.3.06%3A_The_Arrhenius_Law_-_Pre-exponential_Factors#:~:text=As%20temperature%20increases%2C%20molecules%20move,affect%20the%20collision%20frequency%2C%20A.

Even though A is often described as temperature-independent, A is actually affected by temperature because "as temperature increases, molecules move faster; as molecules move faster, they are more likely to collide and therefore affect the collision frequency, A".
I think for us in Chem 14B we can just assume that it's independent!

Valerie Tran 2B
Posts: 105
Joined: Wed Sep 30, 2020 9:48 pm
Been upvoted: 2 times

Re: Frequency Factor

Postby Valerie Tran 2B » Sun Mar 14, 2021 1:45 am

For this class, we can consider it independent because it varies so little but technically it will increase with temperature.

Joshua_Chan_3K
Posts: 46
Joined: Wed Nov 18, 2020 12:27 am

Re: Frequency Factor

Postby Joshua_Chan_3K » Sun Mar 14, 2021 9:27 am

For this class you can probably assume that it won't change. The frequency factor is practically a constant for its own reaction.

Rachael Cohen 3G
Posts: 53
Joined: Sun Dec 13, 2020 12:17 am

Re: Frequency Factor

Postby Rachael Cohen 3G » Sun Mar 14, 2021 9:29 am

For this class I think we can assume it will not change and that any values we need will be given to us.


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