Psuedo First Order
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Re: Psuedo First Order
A pseudo first order reaction is like a second order reaction that acts like a first order reaction under certain conditions.
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Re: Psuedo First Order
A pseudo rate is considered when there are too many changing concentrations. For instance, it is difficult to calculate the rate when you have k[A][B], and both A and B are changing. As such, you make one significantly larger so that the rate becomes dependent on only the other.
For this example, let's say [A] is significantly larger than [B]. Because of that, the pseudo rate is k'=[B]
For this example, let's say [A] is significantly larger than [B]. Because of that, the pseudo rate is k'=[B]
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Re: Psuedo First Order
Is the rate always going to depend on the reactant with smallest concentration?
Douglas Nguyen 2J wrote:A pseudo rate is considered when there are too many changing concentrations. For instance, it is difficult to calculate the rate when you have k[A][B], and both A and B are changing. As such, you make one significantly larger so that the rate becomes dependent on only the other.
For this example, let's say [A] is significantly larger than [B]. Because of that, the pseudo rate is k'=[B]
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Re: Psuedo First Order
Noe BM 1J wrote:Is the rate always going to depend on the reactant with smallest concentration?Douglas Nguyen 2J wrote:A pseudo rate is considered when there are too many changing concentrations. For instance, it is difficult to calculate the rate when you have k[A][B], and both A and B are changing. As such, you make one significantly larger so that the rate becomes dependent on only the other.
For this example, let's say [A] is significantly larger than [B]. Because of that, the pseudo rate is k'=[B]
I think it's the one with the smaller concentration because you just want to focus on one concentration rather than have 2 different concentrations that are changing.
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Re: Psuedo First Order
This is just a question posed towards anyone, but are there any example problems involving pseudo first order (or is this concept even tested at all?
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Re: Psuedo First Order
When concentrations are changing at an excessive rate, a pseudo rate is taken into account. For instance, figuring out the rate when both A and B are changing and you know k[A][B] is challenging. In order to make the rate reliant only on the other, you make one much greater.
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