Steady State Approximation

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Trisha Mantri 3L
Posts: 112
Joined: Fri Sep 24, 2021 5:47 am

Steady State Approximation

Postby Trisha Mantri 3L » Sun Mar 06, 2022 7:41 pm

Could someone explain why steady state approximation is an assumption that can be made? I'm a little confused as to why we can just assume that the formation of reaction intermediates is 0.

Tala Ayoub 1H
Posts: 110
Joined: Fri Sep 24, 2021 5:08 am

Re: Steady State Approximation

Postby Tala Ayoub 1H » Sun Mar 06, 2022 7:43 pm

I believe that it is because it is based on the assumption that one intermediate in the reaction mechanism is consumed as quickly as it is generated. Therefore, its concentration remains the same in a duration of the reaction.

Dolores B
Posts: 20
Joined: Mon Jan 09, 2023 9:41 am

Re: Steady State Approximation

Postby Dolores B » Sun Mar 12, 2023 10:22 pm

The intermediate is neither one of the reactants nor one of the products so it only lasts for a short time during the course of the reaction which is why it is consumed as quickly as it is regenerated.

Hamna_Khan_2E
Posts: 35
Joined: Mon Jan 09, 2023 9:03 am

Re: Steady State Approximation

Postby Hamna_Khan_2E » Sat Mar 18, 2023 11:23 pm

Hi!

This assumption is based on the idea that the rate of production of the intermediate species is equal to its rate of consumption, or that the intermediate species is generated and eaten at the same rate. Thus, the concentration of the intermediate species is said to be in a "steady state."

Hope this helps!


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