Difference between activation energy and free energy of activation

Moderators: Chem_Mod, Chem_Admin

Julie Tran 3C
Posts: 101
Joined: Fri Sep 24, 2021 7:05 am
Been upvoted: 4 times

Difference between activation energy and free energy of activation

Postby Julie Tran 3C » Thu Mar 10, 2022 12:43 am

On the syllabus, it says that we have to know the difference between activation energy and free energy of activation. What is free energy of activation? Is this the same thing as free energy, the change in free energy, or something else?

Charmaine Ho 2G
Posts: 100
Joined: Fri Sep 24, 2021 7:06 am
Been upvoted: 2 times

Re: Difference between activation energy and free energy of activation

Postby Charmaine Ho 2G » Thu Mar 10, 2022 12:57 am

I believe free energy of activation is Gibbs free energy.
Free energy is the available energy in the system that is able to do work.
Activation energy is the amount of energy required to overcome the energy barrier for the reaction to occur.

Irene Kim 3E
Posts: 106
Joined: Fri Sep 24, 2021 6:49 am

Re: Difference between activation energy and free energy of activation

Postby Irene Kim 3E » Sat Mar 12, 2022 11:57 pm

Free energy of activation refers to Gibbs free energy, which we can derive by subtracting the energy of the reactants from the energy of the products. This gives us the amount of energy available to do work (total free energy in the system). The activation energy is derived by subtracting the maximum energy of the reaction (during the transition state) from the energy of the reactants. This gives us the minimum amount of energy needed for that particular reaction to occur.

Prachi Roy 2K
Posts: 41
Joined: Mon Jan 09, 2023 9:30 am

Re: Difference between activation energy and free energy of activation

Postby Prachi Roy 2K » Sun Mar 12, 2023 11:54 pm

Also, I would keep in mind that activation energy must always be positive, whereas free energy (referring to Gibb's free energy) can be either negative (pertaining to a spontaneous reaction) or positive.

James Yu 3C
Posts: 53
Joined: Mon Jan 03, 2022 9:53 am

Re: Difference between activation energy and free energy of activation

Postby James Yu 3C » Tue Mar 14, 2023 12:37 pm

I think something else to consider is that the gibb's free energy doesn't always indicate whether the reactants can exceed the activation energy, since gibb's energy only depends on final and initial states and does not depend on the pathway (which is affected by activation energy).


Return to “Experimental Details”

Who is online

Users browsing this forum: No registered users and 2 guests