Achieve question #4

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906155996
Posts: 46
Joined: Fri Sep 29, 2023 10:36 am

Achieve question #4

Postby 906155996 » Thu Jan 11, 2024 3:49 pm

Achieve question #4
Hi! I am confused on how to go thorugh the process on question 4, where is states, At a certain temperature, the given reaction has an equilibrium constant of Kp=389. PCL3(g)+Cl2(g) ---> <-- PCL5(g)
PCl5 is placed in a sealed container at an initial pressure of 0.0680 bar. What is the total pressure at equilibrium? Any advice would help!

Hao Tam Tran 3H
Posts: 121
Joined: Fri Sep 29, 2023 11:09 am

Re: Achieve question #4

Postby Hao Tam Tran 3H » Thu Jan 11, 2024 3:56 pm

Hi!

To start, you should make an ICE chart (it should not matter if you do the reverse reaction, the order is only important for the K formula itself for which one goes on top).

PCl3 + CL2 <> PCL5
I 0 0 0.068
C +x +x -x
E x x 0.068-x
We can then solve Kp = 389 = (0.068-x)/(x^2) by solving for x and then using the quadratic formula. Use this x to find the equilibrium partial pressures of all the reactants and products. To find the total pressure, add all these partial pressures together.


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