s-electrons and p-electrons  [ENDORSED]

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Christy Lee 2H
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Joined: Fri Sep 29, 2017 7:07 am
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s-electrons and p-electrons

Postby Christy Lee 2H » Sat Oct 21, 2017 10:46 am

Can someone explain why s-electrons have a lower energy than p-electrons? Confused because their energy differs even though they're in the same shell??

Rebecca Cheung 1E
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Joined: Fri Sep 29, 2017 7:04 am

Re: s-electrons and p-electrons  [ENDORSED]

Postby Rebecca Cheung 1E » Sat Oct 21, 2017 10:47 am

Because of the different shapes of s and p orbitals, in a multi-electron system the energy of s-orbitals is lower than the energy of p-orbitals because of the small differences in attraction they feel from the nucleus. S-orbitals is spherical and symmetrical with no nodal planes, while p-orbitals are non symmetric and have a nodal plane so they feel different pulls from the nucleus.

skalvakota2H
Posts: 52
Joined: Sat Jul 22, 2017 3:01 am

Re: s-electrons and p-electrons

Postby skalvakota2H » Sun Oct 22, 2017 10:56 am

The idea is that since s-electrons do not have a node at the nucleus as opposed to p-electrons with nodes. This difference in shape allows for more electron penetration by the s-electrons. As a result, this decreases the shielding of the s-electrons, and getting closer to the nucleus adds more nuclear charge which lowers the energy. Thus, the energy of s-electrons is relatively lower to that of the p-electrons.


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