Topic 1E number 13 a)

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Ashley Zhu 1A
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Topic 1E number 13 a)

Postby Ashley Zhu 1A » Wed Oct 17, 2018 7:00 pm

Part a) of number 13 asks for the ground-state electron configuration for silver, and the answer says it's [Kr] 4d^10 5s^1. The textbook explicitly stated that only chromium and copper were exceptions to the general electron configuration rules and didn't include silver but the answer suggests otherwise. Could someone explain why this happens and what other metals might be an exception?

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Re: Topic 1E number 13 a)

Postby Chem_Mod » Thu Oct 18, 2018 9:53 am

Ag is in period 5 right below Copper, and this shows the same trend as Chromium and Copper. The metal wants either a "half full" d subshell (d5) or a "full" d subshell (d10). It's more stable if metal gives up one of 5s electrons to fill the 4d subshell.

Ashley Zhu 1A
Posts: 69
Joined: Fri Sep 28, 2018 12:16 am

Re: Topic 1E number 13 a)

Postby Ashley Zhu 1A » Fri Oct 19, 2018 4:29 pm

Thank you! Does this rule apply to gold also? And in that case, why is the e- configuration for tungsten(W), which is in period 6 under chromium, [Xe]4f^14 5d^4 6s^2 and not [Xe] 4f^14 5d^5 6s^1? (part e) of the same problem)


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