orbitals

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805098281
Posts: 30
Joined: Fri Sep 28, 2018 12:26 am

orbitals

Postby 805098281 » Fri Oct 19, 2018 4:24 pm

What do "px-, py-, and pz" stand for and how are they relevant. I see them listed next to orbitals but I have no idea what they are supposed to convey.

Samantha Kwock 1D
Posts: 61
Joined: Fri Sep 28, 2018 12:24 am

Re: orbitals

Postby Samantha Kwock 1D » Fri Oct 19, 2018 4:43 pm

"px, py, and pz" describe the orientation of the lobes of the p orbitals. For the px orbital, the two lobes lie along the x axis. For the py orbital, the lobes lie along the y axis. For the pz orbital, the lobes lie along the z axis.

Kathryn 1F
Posts: 66
Joined: Fri Sep 28, 2018 12:19 am

Re: orbitals

Postby Kathryn 1F » Fri Oct 19, 2018 4:44 pm

They represent which axis the orbital goes around, or which mathematical function is used to form it. In the case of px, the orbital goes about the x axis with the nodal plane on the zy plane.

Danny Elias Dis 1E
Posts: 60
Joined: Fri Sep 28, 2018 12:19 am

Re: orbitals

Postby Danny Elias Dis 1E » Fri Oct 19, 2018 9:06 pm

Can "l" be any number less than "n-1," or must it be n-1?

Madeline Motamedi 4I
Posts: 62
Joined: Fri Sep 28, 2018 12:23 am

Re: orbitals

Postby Madeline Motamedi 4I » Sat Oct 20, 2018 2:34 pm

For the p orbital, we have x, y, and z since those are the three orientations for the p orbital. What happens with the orbitals after this? For the d orbitals we're dealing with 5 axis, so would we have v, w, x, y, z? or do we just use numbers to refer to these orbitals?

Jonathan Pai 2I
Posts: 121
Joined: Fri Sep 28, 2018 12:27 am

Re: orbitals

Postby Jonathan Pai 2I » Sat Oct 20, 2018 5:36 pm

Danny, l can be any number lower than n-1. For example, if n=4, l is not automatically 3. l can still be 0, 1, 2, or 3.

Jonathan Pai 2I
Posts: 121
Joined: Fri Sep 28, 2018 12:27 am

Re: orbitals

Postby Jonathan Pai 2I » Sat Oct 20, 2018 5:41 pm

Madeline, the orbitals are based off the axes, so there would be no v or w, only x, y, and z.

In the d orbital, there is xy, xz, yz, x^2y^2, z^2. If you see the pictures in the books, the xy, xz, yz ones have the little orbitals in between those stated axes. So for xy, you can see that the 4 globs are in between the x axis and y axis, but not along/through it. However when it is x^2y^2 or z^2, the globs go through/along that axis.


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