order
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Re: order
D-orbitals have a slightly lower energy level than s-orbitals in the same period, therefore d-orbitals are filled with electrons first before s-orbitals. For example, the 3d orbital would be filled with electrons before the 4s orbital.
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Re: order
With some exceptions where the s orbital is lower energy, since the d orbital is in a different shell you order that first. Eg. 4d then 5s.
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